Two Ukrainian athletes won more than a single Olympic medal, while all of their competitors in sprint canoeing won at least a medal.

Ukrainian athletes wore Bosco uniforms for the first time at the 2008 Summer Olympics in Beijing.

Before 1994, Ukrainian athletes were a part of the Soviet Union at the Olympics from 1952 to 1988.

Hanna Shelekh (born 14 July 1993) is a Ukrainian athlete who competes in the pole vault.

Olha Skrypak (born 2 December 1990) is a Ukrainian athlete who competes in the long-distance events.

Mariia Pomazan (15 October 1988) is a Ukrainian Paralympic athlete.

Alina Fyodorova (born 31 July 1989) is an Ukrainian athlete competing in heptathlon.

Andriy Naumov (born 21 December 1973) is a Ukrainian athlete who specialises in long distance running, principally the marathon.

Previously, Ukrainian athletes competed for the Unified Team at the 1992 Summer Olympics.

Ukrainian athletes competed in athletics, judo, table tennis, wheelchair volleyball, swimming and weightlifting.