Even at lower temperatures, individual molecules of a liquid can evaporate if they have more than the minimum amount of kinetic energy required for vaporization.
The molecules of water will evaporate from my mortal shell, float into the air and join clouds high above all these earthly troubles.
That may not be the right word... I guess I'm asking "but what if the molecule in question can evaporate too?"
If sufficient energy is provided, the molecule or atom may reach the escape velocity of the planet and "evaporate" into space.
The 2nd requirement is also often the reason why some molecules do not evaporate easily.
The gas-phase ions form after the remaining solvent molecules evaporate, leaving the analyte with the charges that the droplet carried.
As the Klingons pressed their blades into Deanna's neck her molecules glimmered and evaporated.
Inside the oven, the molecules of the jar material immediately evaporate.
Supplying more heat usually breaks the bonds and causes the adsorbed molecules to evaporate.
Because only the hottest molecules, the ones with the most energy, actually evaporate, only the cooler molecules are left behind in the liquid.