Defoe went on to score his first international hat-trick which was the first hat-trick at the new Wembley.
England lost the match 2-1, their first defeat at the new Wembley.
Corr also lead out the first ever Scotland squad to play at the new Wembley.
Ronnie Henry was the first ever player to lift a competitive club trophy at the new Wembley.
Celtic were the first Scottish team to win a trophy at the new Wembley.
The new Wembley boasts an arch four times the size of the towers.
The first England game at the new Wembley was on 1 June 2007, against Brazil.
It was Liverpool's first appearance at the new Wembley.
The second game was a friendly match against Italy on 27 March 2002 while the new Wembley was being built.
He scored in a 2-1 loss to Germany in a friendly at the new Wembley in 2007.